Search results for "ION ABSTRACTION"

showing 3 items of 3 documents

Preparation and Characterization of P2 BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes

2018

Four-membered rings with a P2BCh core (Ch = S, Se) have been synthesized via reaction of phosphinidene chalcogenide (Ar*P=Ch) and phosphaborene (Mes*P=BNR2). The mechanistic pathways towards these rings are explained by detailed computational work that confirmed the preference for the formation of P–P, not P–B, bonded systems, which seems counterintuitive given that both phosphorus atoms contain bulky ligands. The reactivity of the newly synthesized heterocycles, as well as that of the known (RPCh)n rings (n = 2, 3), was probed by the addition of Nheterocyclic carbenes, which revealed that all investigated compounds can act as sources of low-coordinate phosphorus species. peerReviewed

BOND COVALENT RADIIChalcogenidePHOSPHINIDENE ADDUCTSSULFURchemistry.chemical_element010402 general chemistryRing (chemistry)ION ABSTRACTION01 natural sciencesMedicinal chemistryCatalysischemistry.chemical_compoundELEMENTSmain-group heterocyclesReactivity (chemistry)N-heterocyclic carbenesMETHYLENEPHOSPHINEta116epäorgaaniset yhdisteetphosphinidene chalcogenidesheterocycleskemiallinen synteesiphosphaborenes010405 organic chemistryPhosphorusOrganic ChemistryGeneral ChemistryREAGENT0104 chemical sciencesCharacterization (materials science)PHOSPHORUSchemistryPhosphinideneinorganic compoundsSULFURIZATIONchemical synthesisX-RAY-STRUCTUREChemistry - A European Journal
researchProduct

Cartoon filter via adaptive abstraction

2016

We propose a non-parametric methodology to realize abstraction images.The redundant wavelet "a trous" algorithm is applied for details detection.An multi-scale circular median filter is used as a smoothing filter.The proposed algorithm is simple and fast on low-cost entry-level hardware. Abstraction in computer graphics defines a procedure that discriminates the essential information that is worth keeping. Usually details, that correspond to higher frequency components, allow to distinguish otherwise similar images. Vice versa, low frequencies are related to the main information, which are larger structures. Contours themselves may also be identified by high frequencies and separate each pi…

Cartoon filterRedundant wavelet02 engineering and technologyEdge-preserving smoothingRedundant waveletsMultiresolution abstractionComputer graphicsCircular median filterWaveletFast multi-scale median0202 electrical engineering electronic engineering information engineeringMedian filterMedia TechnologyComputer visionElectrical and Electronic EngineeringMathematicsAbstraction (linguistics)1707Settore INF/01 - Informaticabusiness.industryEdge preserving smoothingWavelet transform[INFO.INFO-CV]Computer Science [cs]/Computer Vision and Pattern Recognition [cs.CV]020207 software engineeringFilter (video)Mathematical morphologyEuclidean distance transformSignal Processing020201 artificial intelligence & image processingComputer Vision and Pattern RecognitionArtificial intelligencebusinessAlgorithmSmoothing
researchProduct

Information Abstraction from Crises Related Tweets Using Recurrent Neural Network

2016

Social media has become an important open communication medium during crises. The information shared about a crisis in social media is massive, complex, informal and heterogeneous, which makes extracting useful information a difficult task. This paper presents a first step towards an approach for information extraction from large Twitter data. In brief, we propose a Recurrent Neural Network based model for text generation able to produce a unique text capturing the general consensus of a large collection of twitter messages. The generated text is able to capture information about different crises from tens of thousand of tweets summarized only in a 2000 characters text.

Computer science02 engineering and technologyCrisis managementcomputer.software_genreData scienceTask (project management)World Wide WebInformation extractionRecurrent neural network020204 information systems0202 electrical engineering electronic engineering information engineeringText generation020201 artificial intelligence & image processingInformation abstractionSocial mediaOpen communicationcomputer
researchProduct